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Journal of the Mexican Chemical Society
Print version ISSN 1870-249X
Abstract
DHASARATHAN, Saranya; SHUNMUGAPERUMAL, Selvaraj and KAMATCHI SELVARAJ, P.. Synthesis of Ferrocene Based Schiff Bases Possessing Different Metal Ion Sensing Aptitude and Partaking Antimicrobial Activity. J. Mex. Chem. Soc [online]. 2022, vol.66, n.3, pp.343-361. Epub Apr 10, 2023. ISSN 1870-249X. https://doi.org/10.29356/jmcs.v66i3.1677.
Schiff bases comprised of highly reactive ferrocene derivatives and normal aromatic moiety have been prepared successfully. Spectral variations noticed in the spectra of newly synthesized receptors for the addition of different metal ions discloses the multi metal ion sensing ability of the prepared sensors. Harmonization of Cu2+ ions with receptor originate as MLCT band in the visible region. Shrewdness made from the data obtained from cyclic voltammetry studies give an idea about the concentration of metal ions needed for effective sensing. In vitro antimicrobial studies and H- bond energy calculation for the interaction between the above sensory materials and proteins of selected microorganisms using molecular docking studies disclosures the antifungal activity of newly prepared materials.
Keywords : Unsymmetrical Schiff bases; ferrocene; cation sensors; azomethine; binding attitude; molecular docking.