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Journal of the Mexican Chemical Society
Print version ISSN 1870-249X
Abstract
MORALES-NAVA, Rosmarbel and OLIVO, Horacio F.. Synthetic Applications of Sulfur-based Chiral Auxiliaries in Asymmetric Syntheses. J. Mex. Chem. Soc [online]. 2019, vol.63, n.3, pp.93-104. Epub Sep 14, 2020. ISSN 1870-249X. https://doi.org/10.29356/jmcs.v63i3.527.
This mini-review intends to present one of the themes that has driven my research in developing methodology for the synthesis of natural products and important biologically active molecules. Sulfur-based chiral auxiliaries from aminoacids have been shown to have superior qualities in many cases to other well-known chiral auxiliaries. Some applications of these auxiliaries include acetate aldol reactions, resolution of racemic mixtures, Michael additions, intramolecular thio-Michael/aldol cyclization cascade reactions, and synthesis of natural products, including a new practical and efficient indene-based thiazolidinethione auxiliary.
Keywords : thiazolidinethione; oxazolidinethione; chiral auxiliary; aldol reaction; natural products..