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Journal of the Mexican Chemical Society

Print version ISSN 1870-249X

Abstract

RODRIGUEZ-CASTELLANOS, Andrés; LOPEZ-TORRES, Ernesto  and  SOLORZA-FERIA, Omar. Solar-Hydrogen-Fuel Cell Prototype as a Source of Renewable Energy Generation. J. Mex. Chem. Soc [online]. 2007, vol.51, n.2, pp.55-58. ISSN 1870-249X.

A small renewable energy prototype is presented, integrated by a solar photovoltaic module used for electrolysis of water where the resulting hydrogen was fed to a regenerative fuel cell for a clean electricity generation. A photovoltaic module provided DC power to an electrolyzer, to produce 56 cm3/min of hydrogen which is fed to a fuel cell and generate electricity. This prototype was designed and manufactured to show the future energy scenario of renewable energy. For water electrolysis, powders of RuCoOx were used as anode and nanometric Pt powders as cathode catalysts in a polymer electrolyte membrane. Anode catalyst was prepared by pyrolysis processes and annealed at 550°C. The catalysts were applied to an electrode membrane assembly (MEA) and studied gal-vanostatically and under solar illumination in an electrolysis cell. A high electrochemical performance of the electrolyzer was obtained with 0.25 A cm-2 at 1.87 V for each single MEA, at 30 °C and atmospheric pressure of 585 mmHg in Mexico City. The fuel cell stack prototype was also designed and manufactured with 10 MEAs containing 0.4 mg/cm2 of 20 wt.% Pt as anode and cathode, to generate electrical energy to power on a portable 3.5 watts TV.

Keywords : Renewable energy; electrolyzer; hydrogen; fuel cell.

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