Abstract

BING LIU, Xiao; LIU, Yang  and  LIN HU, Yu. Highly Active Benzotriazolium Ionic Liquid-modified Periodic Mesoporous Organosilica Supported Samarium/Lanthanum Nanoparticles for Sustainable Transformation of Carbon Dioxide to Cyclic Carbonates. J. Mex. Chem. Soc [online]. 2020, vol.64, n.3, pp.201-217.  Epub June 04, 2021. ISSN 1870-249X.  https://doi.org/10.29356/jmcs.v64i3.1198.

A novel type of multifunctional nanocatalysts (La-/Sm-PMO-ILCl) based on the immobilization of benzotriazolium ionic liquid and further incorporation of samarium acetate or lanthanum acetate onto periodic mesoporous organosilica were afforded for the cycloaddition of CO2 and epoxides to produce cyclic carbonates. In consequence of the intramolecular synergistic effect between samarium sites of periodic mesoporous organosilica and homogeneously dispersed basic sites of ionic liquid, the powerful catalyst Sm-PMO-ILCl offered superior catalytic performance with ultra high yields and selectivities in the cycloaddition reaction without the addition of any solvent and cocatalyst. Moreover, the catalyst Sm-PMO-ILCl could be easily recovered by filtration and reused for at least five runs without any significant loss of its catalytic activity.

Keywords : Supported ionic liquid; cycloaddition; cyclic carbonates; carbon dioxide.

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