Investigación

 

Study of dynamical properties in β-TCP/CH layers

 

A. Mina^a, J.C. Caicedo^a*, and W. Aperador^b

 

^a Tribology, Powder Metallurgy and Processing of Solid Recycled Research Group, Universidad del Valle, Cali-Colombia, * Tel/Fax Number: 57+2+ 3122270 Ext 27 e-mail: jcaicedoangulo1@gmail.com.

^b Departament of Engineering, Universidad Militar Nueva Granada, Bogotá-Colombia.

 

Received 20 August 2014;
accepted 5 February 2015

 

Abstract

β-Tricalcium phosphate/Chitosan (β-TCP/Ch) coatings were deposited on 316L stainless steel (316L SS) substrates by a cathodic electro-deposition technique at different coating compositions. The crystal lattice arrangements were analyzed by X-Ray diffraction (XRD), and the results indicated that the crystallographic structure of β-TCP was affected by the inclusion of the chitosan content. The changes in the surface morphology as a function ofincreasing chitosan in the coatings via scanning electron microscopy (SEM) and atomic force microscopy (AFM) showed the root-mean squares hardness of the β-TCP/Ch coatings decreased by further increasing chitosan percentage. The elastic-plastic characteristics of the coatings were determined by conducting nanoindentation test, indicating that the increase if chitosan percentage is directly related to increasing the hardness and elastic modulus of the β-TCP/Ch coatings. Tribological characterization was performed by scratch test and pin-on-disk test to analyze the changes in the surface wear the β-TCP/Ch coatings. Finally, the results indicated an improvement in the mechanical and tribological properties of the β-TCP/Ch coatings as a function of increasing of the chitosan percentage.

Keywords: Surfaces; monolayers; coatings; electrochemical techniques; hardness.

 

PACS: 68.47.Gh; 75.70.Ak; 68.35.Ct; 82.45.Bb; 62.20.Qp

 

DESCARGAR ARTÍCULO EN FORMATO PDF

 

Acknowledgments

This research was supported by the Universidad Militar Nueva Granada, Bogotá-Colombia project IMP-ING-1775 and the Excellence Center for Novel Materials (CENM) at Universidad del Valle in Colombia under Contract RC-043-2005 with Colciencias.

 

References

1. J.B. Brunski, in: B.D. Ratner, A.S. Hoffman, F.J. Schoen, and J.E. Lemons (Eds.), Biomaterials Science an Introduction to Materials in Medicine, 2nd ed., (Elsevier Academic Press, San Diego, 2004) p. 137.         [ Links ]

2. B. Karim, J. Jean, D. Mainard, P. Elisabeth, and N. Patrick, Biomaterials 17 (1996) 491.         [ Links ]

3. E. Salahinejad et al., PLoS ONE 8 (2013) 1-8.         [ Links ]

4. M. Mozafari et al., International Journal of Nanomedicine 8 (2013) 1665-1672.         [ Links ]

5. S.M. Naghib, M. Ansari, A, Pedram, F. Moztarzadeh, and A. Feizpour, M. Mozafari, International Journal of Electrochemical Science 7 (2012) 2890-2903.         [ Links ]

6. E. Salahinejad et al., Journal of Biomedical Nanotechnology 9 (2013) 1327-35.         [ Links ]

7. M.J. Cross, E.N. Parish, and J. Bone, Joint Surg Br 87 (2005) 1073-6.         [ Links ]

8. T. Jinno, D.T. Davy, and V.M. Goldberg, J. Arthroplasty. 17 (2002) 902-9.         [ Links ]

9. X. Pang, and I. Zhitomirsky, Colloid and Interface Science. 330 (2009) 323-329.         [ Links ]

10. D. Peña, H. Estupiñan, H. Cordoba, and C. Vasquez, Rev. Fac. Ing. Univ. Antioquia (54) (2010) 15-23.         [ Links ]

11 . Y. Abe, T. Kokubo and T. Yamamuro, Materials Science. Materials in Medicine 1 (1990) 233.         [ Links ]

12. L. Pighinelli and M. Kucharska, Journal of Biomaterials and Nanobiotechnology 4 (2013) 20-29.         [ Links ]

13. S.-J. Ding, Dental Materials Journal 25 (2006) 706-712.         [ Links ]

14. M. Kucharska, A. Niekraszewicz, M. Wisniewska-Wrona, E. Wesolowska and H. Struszczyk, Progresson Chemistry and Application of Chitin and Its Derivatives. 3 (2003) 69-72.         [ Links ]

15. G.R. Bamwenda, K. Sayama, and H. Arakawa, J. Photochem. Photobiol., A Chem. 122 (1999) 175.         [ Links ]

16. O. Bohnke, C. Bohnke, and G. Robert, Solid State Ion. 6 (1982) 121.         [ Links ]

17. D. Davazoglou, A. Donnadieu, and A. Donnadicu, Solar Energy Mat. 71 (1988) 379.         [ Links ]

18. E. Salahinejad, M.J. Hadianfard, D.D. Macdonald, M. Mozafari, D. Vashaee, and L. Tayebi, Materials Letters 88 (2012) 5-8.         [ Links ]

19. R. Hurdich, Electron Lett. 11 (1975) 142.         [ Links ]

20. K.D. Lee, Thin Solid Films 302 (1997) 84.         [ Links ]

21. P.M.S. Monk, and L.S. Chester, Electrochim. Acta 38 (1993) 1521.         [ Links ]

22. A.I. Inamdar, S.H. Mujawar, V. Ganesan and P.S. Patil, Nanotechnol 19 (2008) 325706.         [ Links ]

23. E.M. Castro, H A. Estupiñan, and D.Y. Peña, Scientia et Technica 13 (2007) 36.         [ Links ]

24. D.S. Metsger, M.R. Rieger, and D.W. Foreman, J. Mater Sci Mater Med 10 (1999) 9-17.         [ Links ]

25. X. Guo, L. Lee, L.P. Law, H. Chow, R. Rosier, and C. Cheng, J. Orthop. Res 20 (2002) 740-746.         [ Links ]

26. S.S. Banerjee, S. Tarafder, N.M. Davies, A. Bandyopadhyay, and S. Bose, Acta Biomaterialia. 6 (2010) 4167-4174.         [ Links ]

27. E.T. den Braber, J.E. de Ruijter, and L.A. Ginsel, Biomaterials 17 (1996) 2037-2044.         [ Links ]

28. M. Zhang, X.H. Li, Y.D. Gong, N.M. Zhao, and X.F. Zhang, Biomaterials. 23 (2002) 2641-2648.         [ Links ]

29. R. Martínez H. Estupiñan, D. Peña, and P. Mohan, Scientia et Technica. 36 (2007) 36.         [ Links ]

30. W.C. Oliver and G.M. Pharr, Journal of Materials Research 7-6 (1992) 1564-1583.         [ Links ]

31. W. Jiawei, Journal of Biomedical materials Research. Part. A. 76 (2006) 503-511.         [ Links ]

32. A. Tejada, C. Pina, S. Martínez, and G. Ávila, Rev. Mex. Fis. 5 (2004) 187-192.         [ Links ]

33. G. Tomoaia, A. Mocanu, I. Vida-Simiti, N. Jumate, L. Dorel Bobos, and O. Soritau, M. Tomoaia-Cotisel, Materials Science and Engineering: C, 37 (2014) 37-47.         [ Links ]

34. G.S. Kim, S.Y. Lee, and J.H. Hahn, Surf. Coat. Technol. 171 (2003) 91-95.         [ Links ]

35. J. Zhang, W. Liu, V. Schnitzler, F. Tancret, and J. Bouler, Acta Biomaterialia. 10 (2014) 1035-1049.         [ Links ]

36. G. Cabrera, J.C. Caicedo, C. Amaya, L. Yate, J. Muñoz Saldana, and P. Prieto, Materials Chemistry and Physics. 125 (2011) 576-586.         [ Links ]

37. V.V. Hajek, K. Rusnak, J. Vlcek, L. Martinu and H.M. Hawthorne, Wear 213 (1997) 80-86.         [ Links ]

38. J.C. Caicedo et al., Applied Surface Science. 256 (2010) 5898-5904.         [ Links ]

39. G.S. Kim, S.Y. Lee, and J.H. Hahn, Surface and Coatings Technology. 171 (2002) 91-95.         [ Links ]

40. P.J. Burnett and D.S. Rickerby, Thin Solid Films. 154 (1987) 403-416.         [ Links ]

41. J.C. Caicedo, G. Bejarano, M.E. Gómez, P. Prieto, C. Cortez, and J. Munoz, Phys. Stat. Sol. 4 (2007) 4127-4133.         [ Links ]

42. J. Romero, A. Lousa, J. Esteve, and E. Martínez, Applied Physics A: Materials Science & Processing. 77 (2003) 419-427.         [ Links ]

43. J.F. Archard. Journal of Applied Physics. 24 (1953) 981.         [ Links ]

44. P. Nledengvist and S. Hogmark, Tribology International. 30 (1997) 507-516.         [ Links ]

45. L. Ipaz, J.C. Caicedo, J. Esteve, F.J. Espinoza-Beltran, and G. Zambrano, Applied Surface Science 258 (2012) 3805- 3814.         [ Links ]

46. S.J. Bull, D.S. Rickerby, A. Matthews, A. Leyland, A.R. Pace, and J. Valli, Surf. Coat. Technol. 36 (1988) 503-517.         [ Links ]

47. J.M Lackner, L. Major, and M. Kot, Bull. Pol. Ac.: Tech. 59 (2011) 343-355.         [ Links ]