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Journal of applied research and technology
versión On-line ISSN 2448-6736versión impresa ISSN 1665-6423
Resumen
LOPEZ LUNA, Mauricio y CEDENO-CAERO, Luis. Tungsten based catalysts for oxidative desulfurization: surface species and partially reduced systems as key features to improve the activity. J. appl. res. technol [online]. 2018, vol.16, n.6, pp.455-465. ISSN 2448-6736.
Tungsten oxide based catalysts for the oxidative desulfurization (ODS) process of dibenzothiophene compounds using H2O2 as oxidizing agent were studied. Catalysts were characterized by TPR-H2, SEM-EDS, XRD, N2-physisorption and Raman spectroscopy. Different surface tungsten oxide species were detected and related to the ODS activity, furthermore, the predominance of the surface tungsten oxide species was associated with the tungsten loading. Moreover, in some catalysts, WO3 crystals were detected and their role in the performance of the catalysts was studied too. Finally, the catalysts were partially reduced and tested in the ODS reaction, the reduced catalysts exhibited high activity and an improvement of H2O2 to sulfones yield.
Palabras llave : ODS; Tungsten oxide; TPR-H2; Alumina; Low sulfur diesel; Dibenzothiophene compounds.
