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Revista de la Sociedad Química de México

 ISSN 0583-7693

CORTEZ, Norma Aidé et al. Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands. []. , 48, 1, pp.53-57. ISSN 0583-7693.

^len^aA library of chiral Schiff base ligands was synthesized from aromatic aldehydes and chiral amino alcohols. These ligands were then screened as catalysts in the asymmetric ring opening of meso-cyclohexene epoxide with phenyllithium to give (1S,2R)-phenylcyclohexanol in 9-67% ee.^les^aSe ha sintetizado una biblioteca de ligandos quirales tipo base de Schiff a partir de aldehídos aromáticos y aminoalcoholes quirales. Se midió la capacidad catalítica de estos ligandos en la apertura asimétrica del anillo de meso-epóxido de ciclohexeno con fenillitio para dar (1S,2R)-fenilciclohexanol con 9-67% ee.

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