SILAGHI-DUMITRESCU, Luminita et al. Bromination of (AsPh₂)₂O: The Structure of Tribromo-Diphenylarsenic (V). []. , 44, 2, pp.134-138. ISSN 0583-7693.

^len^aBromination of (AsPh₂)₂O leads to cleavage of the oxo-bridge with formation of the new organoarsenic (V) bromide, AsPh₂Br₃. A crystal structure determination shows that the compound is a trigonal bipyramidal monomer with crystallographically imposed two-fold symmetry and one shorter, equatorial, and two longer, axial bromines. There are weak C-H... π and Br...Br intermolecular interactions in the solid phase.^les^aLa bromación de (AsPh₂)₂O conduce a la ruptura del puente oxo con la formación de un nuevo bromuro organoarsénico (V), AsPh₂Br₃. La determinación de la estructura cristalina muestra que el compuesto es un monómero de bipirámide trigonal con simetría cristalográfica doble, y un bromo ecuatorial y dos bromos axiales. Existen interacciones intermoleculares débiles C-H... π and Br...Br en fase sólida.

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