<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>1665-3521</journal-id>
<journal-title><![CDATA[Superficies y vacío]]></journal-title>
<abbrev-journal-title><![CDATA[Superf. vacío]]></abbrev-journal-title>
<issn>1665-3521</issn>
<publisher>
<publisher-name><![CDATA[Sociedad Mexicana de Ciencia y Tecnología de Superficies y Materiales A.C.]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S1665-35212015000400119</article-id>
<title-group>
<article-title xml:lang="es"><![CDATA[Crecimiento de Películas de TiO 2 por electrodeposición pulsada: Influencia de la frecuencia de los pulsos de voltaje]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Castillo-Ballesteros]]></surname>
<given-names><![CDATA[A.]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Zapata-Torres]]></surname>
<given-names><![CDATA[M.]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Zapata-Navarro]]></surname>
<given-names><![CDATA[A.]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Fernández Muñoz]]></surname>
<given-names><![CDATA[J.L.]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Guillén-Rodríguez]]></surname>
<given-names><![CDATA[J.]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Valaguez-Velazquez]]></surname>
<given-names><![CDATA[E.]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Melendez-Lira]]></surname>
<given-names><![CDATA[M.]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
</contrib-group>
<aff id="Af1">
<institution><![CDATA[,PEMEX Exploración y Producción Subdirección de Producción de Aguas Someras]]></institution>
<addr-line><![CDATA[Cd. Del Carmen Campeche]]></addr-line>
</aff>
<aff id="Af2">
<institution><![CDATA[,IPN CICATA ]]></institution>
<addr-line><![CDATA[México D.F.]]></addr-line>
<country>Mexico</country>
</aff>
<aff id="Af3">
<institution><![CDATA[,I.T.E.S.M.  ]]></institution>
<addr-line><![CDATA[ Tamaulipas]]></addr-line>
<country>Mexico</country>
</aff>
<aff id="Af4">
<institution><![CDATA[,Instituto Politécnico Nacional Unidad Profesional Interdisciplinarias en Ingeniería y Tecnologías Avanzadas ]]></institution>
<addr-line><![CDATA[México D.F.]]></addr-line>
<country>Mexico</country>
</aff>
<aff id="Af5">
<institution><![CDATA[,IPN CINVESTAV Departamento de Física]]></institution>
<addr-line><![CDATA[México D.F.]]></addr-line>
<country>Mexico</country>
</aff>
<pub-date pub-type="pub">
<day>00</day>
<month>00</month>
<year>2015</year>
</pub-date>
<pub-date pub-type="epub">
<day>00</day>
<month>00</month>
<year>2015</year>
</pub-date>
<volume>28</volume>
<numero>4</numero>
<fpage>119</fpage>
<lpage>123</lpage>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://www.scielo.org.mx/scielo.php?script=sci_arttext&amp;pid=S1665-35212015000400119&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://www.scielo.org.mx/scielo.php?script=sci_abstract&amp;pid=S1665-35212015000400119&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://www.scielo.org.mx/scielo.php?script=sci_pdf&amp;pid=S1665-35212015000400119&amp;lng=en&amp;nrm=iso"></self-uri><abstract abstract-type="short" xml:lang="es"><p><![CDATA[Resumen: Se prepararon películas de TiO2 usando la técnica de electrodeposición pulsada sobre sustratos de acero inoxidable, y se estudió el efecto de la frecuencia de los pulsos de voltaje sobre la cantidad de masa depositada y la morfología de las muestras obtenidas. A la celda electrolítica utilizada se le adicionó un sistema de agitación con un motor de vibraciones microsónicas, para la eliminación de burbujas de hidrógeno producidas durante el crecimiento. Los pulsos de voltaje fueron de -2500 mV en la zona catódica y -500 mV en la zona anódica; con una frecuencia en los pulsos en el rango de 0 a 1 Hz. Posterior al crecimiento de las películas, éstas fueron deshidratadas a 120 °C por 1 hora; y sometidas a un tratamiento térmico a 450 °C por 2 horas en argón. Las propiedades estructurales y morfológicas fueron estudiadas mediante Difracción de Rayos-X y Microscopia Electrónica de Barrido. Los resultados muestran que la agitación de la solución ayuda a mantener estable la corriente durante el crecimiento. Las películas presentaron una estructura amorfa después de la deshidratación, transformándose a cristalina después del tratamiento térmico; la cual corresponde al TiO2 en fase anatasa. La masa depositada y la morfología dependen de la frecuencia de los pulsos de voltaje aplicados durante el crecimiento.]]></p></abstract>
<abstract abstract-type="short" xml:lang="en"><p><![CDATA[Abstract: TiO2 films were grown by pulsed electrodeposition on stainless steel substrates, and they were studied the influence of the frequency of the voltage pulse on the amount of mass deposited and the morphology of the samples. The electrolytic cell was added with a system of agitation with a motor of micro sonic vibrations for the elimination of hydrogen bubbles produced during the growth. The voltage pulses were of - 2500 mV in the cathodic zone and -500 mV in the anodic zone; the frequency of the pulses was between 0 and 1 Hz. After their growth the films were dehydrated at 120°C by one hour; and annealed at 450 °C by 2 hours. The structural and morphologic properties were studied by means of X ray Diffraction and Scanning Electron Microscopy. The results show that the agitation of the solution helps stabilizing/maintaining the current during the growth. The films had an amorphous structure after the dehydration, acquiring the anatasa crystalline structure after thermal annealing. The deposited mass and the morphology depend on the frequency of the applied voltage pulses during the growth.]]></p></abstract>
<kwd-group>
<kwd lng="es"><![CDATA[Películas delgadas]]></kwd>
<kwd lng="es"><![CDATA[electrodepósito]]></kwd>
<kwd lng="es"><![CDATA[TiO2]]></kwd>
<kwd lng="en"><![CDATA[Thin films]]></kwd>
<kwd lng="en"><![CDATA[electrodeposition]]></kwd>
<kwd lng="en"><![CDATA[TiO2]]></kwd>
</kwd-group>
</article-meta>
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