<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>2448-5691</journal-id>
<journal-title><![CDATA[Mundo nano. Revista interdisciplinaria en nanociencias y nanotecnología]]></journal-title>
<abbrev-journal-title><![CDATA[Mundo nano]]></abbrev-journal-title>
<issn>2448-5691</issn>
<publisher>
<publisher-name><![CDATA[Universidad Nacional Autónoma de México, Instituto de Ciencias Aplicadas y Tecnología]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S2448-56912024000200009</article-id>
<article-id pub-id-type="doi">10.22201/ceiich.24485691e.2024.33.69825</article-id>
<title-group>
<article-title xml:lang="es"><![CDATA[Producción fotocatalítica de hidrógeno empleando semiconductores modificados con nanopartículas metálicas]]></article-title>
<article-title xml:lang="en"><![CDATA[Photocatalytic hydrogen production using metal nanoparticle-modified semiconductors]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Ramírez Ortega]]></surname>
<given-names><![CDATA[David]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Guerrero Araque]]></surname>
<given-names><![CDATA[Diana]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Acevedo Peña]]></surname>
<given-names><![CDATA[Próspero]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Zanella]]></surname>
<given-names><![CDATA[Rodolfo]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
</contrib-group>
<aff id="Af1">
<institution><![CDATA[,Universidad Nacional Autónoma de México Instituto de Ciencias Aplicadas y Tecnología ]]></institution>
<addr-line><![CDATA[ ]]></addr-line>
<country>Mexico</country>
</aff>
<aff id="Af2">
<institution><![CDATA[,Universidad Autónoma Metropolitana Departamento de Química ]]></institution>
<addr-line><![CDATA[ ]]></addr-line>
<country>Mexico</country>
</aff>
<aff id="Af3">
<institution><![CDATA[,Instituto Politécnico Nacional Laboratorio Nacional de Conversión y Almacenamiento de Energía ]]></institution>
<addr-line><![CDATA[ ]]></addr-line>
<country>Mexico</country>
</aff>
<pub-date pub-type="pub">
<day>00</day>
<month>12</month>
<year>2024</year>
</pub-date>
<pub-date pub-type="epub">
<day>00</day>
<month>12</month>
<year>2024</year>
</pub-date>
<volume>17</volume>
<numero>33</numero>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://www.scielo.org.mx/scielo.php?script=sci_arttext&amp;pid=S2448-56912024000200009&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://www.scielo.org.mx/scielo.php?script=sci_abstract&amp;pid=S2448-56912024000200009&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://www.scielo.org.mx/scielo.php?script=sci_pdf&amp;pid=S2448-56912024000200009&amp;lng=en&amp;nrm=iso"></self-uri><abstract abstract-type="short" xml:lang="es"><p><![CDATA[Resumen: Este trabajo de revisión se centra en la producción fotocatalítica de hidrógeno empleando agentes de sacrificio y semiconductores modificados con nanopartículas metálicas. Mientras que el uso de agentes de sacrificio reduce la energía requerida para la producción de hidrógeno y elimina los huecos fotogenerados, la modificación superficial de los semiconductores con nanopartículas metálicas cambia el flujo de los portadores de carga fotoinducidos, disminuyendo la recombinación de los pares electrón-hueco y aumentando la cantidad de sitios activos catalíticos para la reducción. Además, se describe el impacto de las técnicas electroquímicas y fotoelectroquímicas en la caracterización de los fotocatalizadores, la interfase semiconductor/electrolito y la modificación que tiene el nivel de Fermi cuando se ponen en contacto estos componentes. Dichas determinaciones electroquímicas brindan información sobre el diagrama de bandas (posiciones de banda de valencia y/o de conducción), estados energéticos del semiconductor, interacción del fotocatalizador con los co-catalizadores, separación de las especies electrón-hueco, aprovechamiento de la iluminación y resistencia a la transferencia de carga. La relación de la actividad fotocatalítica de los semiconductores y su caracterización electroquímica permite comprender los procesos de transferencia de carga involucrados en dicha reacción.]]></p></abstract>
<abstract abstract-type="short" xml:lang="en"><p><![CDATA[Abstract: This review paper focuses on photocatalytic hydrogen production using sacrificial agents and semiconductors modified with metal nanoparticles. While the use of sacrificial agents reduces the energy required for hydrogen production and eliminates the recombination of photogenerated holes, the surface modification of semiconductors with metal nanoparticles changes the flow of photoinduced charge carriers, decreasing the recombination of electron-hole pairs and increasing the number of catalytic active sites for reduction. In addition, the impact of electrochemical and photoelectrochemical techniques on the characterization of the photocatalysts, the semiconductor/electrolyte interface, and the modification of the Fermi level when these components are in contact is described. These electrochemical determinations provide information on the band diagram (valence and/or conduction band positions), energy states of the semiconductor, interaction of the photocatalyst with the co-catalysts, separation of the electron-hole species, use of illumination, and resistance to charge transfer. Establishing a relationship between the photocatalytic activity of semiconductors and their electrochemical characterization allows understand the charge transfer processes involved in such a reaction.]]></p></abstract>
<kwd-group>
<kwd lng="es"><![CDATA[producción fotocatalítica de hidrógeno]]></kwd>
<kwd lng="es"><![CDATA[nanopartículas metálicas]]></kwd>
<kwd lng="es"><![CDATA[fotoelectroquímica]]></kwd>
<kwd lng="en"><![CDATA[photocatalytic hydrogen production]]></kwd>
<kwd lng="en"><![CDATA[metal nanoparticles]]></kwd>
<kwd lng="en"><![CDATA[photoelectrochemistry]]></kwd>
</kwd-group>
</article-meta>
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