Study of Sorption Equilibrium of Biopolymers Alginic Acid and Xanthan with C.I. Disperse Yellow 54
Juan Antonio Lozano–Álvarez,1 Juan Jáuregui–Rincón,1* Guillermo Mendoza–Díaz,2 Refugio Rodríguez–Vázquez,3 and Claudio Frausto–Reyes4
1 Departamento de Ingeniería Bioquímica, Universidad Autónoma de Aguascalientes, Av. Universidad 940 Ciudad Universitaria, Aguascalientes, México. *Responsible author:jjaureg@correo.uaa.mx.
2 Facultad de Química, Universidad de Guanajuato, Noria Alta S/N, Guanajuato, México.
3 Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional, México, D.F., México.
4 Centro de Investigaciones en Óptica, Unidad Aguascalientes. Aguascalientes, México.
]]>Received January 12, 2009
Accepted June 29, 2009
Abstract
Disperse yellow 54 (DY54) was adsorbed onto two biopolymers, alginic acid and xanthan. The adsorption isotherms for the biopolymer–DY54 system showed that the adsorption mechanism can best be described by Zimm–Bragg theory. UV–Visible, FT–IR and MicroRaman studies suggest that DY54 is bounded to both biopolymers alginic acid and xanthan through hydrogen bonding. Keto group of dye and hydroxyl groups of sugar residues from two polysaccharides were the principal functional groups involved in sorption mechanism.
Keywords: Sorption, Biopolymers, Disperse dye, Zimm–Bragg Theory, Hydrogen Bonding.
Resumen
El colorante Amarillo disperso 54 (DY54) fue adsorbido en dos biopolímeros, el ácido algínico y la xantana. Las isotermas de adsorción obtenidas para el sistema biopolímero–DY54 muestran que el mecanismo de adsorción puede ser descrito de la mejor manera por la teoría de Zimm–Bragg. Estudios UV–Visible, IR–TF y MicroRaman sugieren que el DY54 se une a ambos biopolímeros, el ácido algínico y la xantana por medio de puentes de hidrógeno. El grupo cetónico del colorante y los grupos oxhidrilo de los residuos de azúcar de los dos polisacáridos fueron los principales grupos funcionales involucrados en el mecanismo de adsorción.
]]> Palabras clave: Adsorción, biopolímeros, colorante disperso, teoría de Zimm–Bragg, puentes de hidrógeno.
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Acknowledgements
We acknowledge the support of Consejo Nacional de Ciencia y Tecnología, México (Grants No. 063581 and 054792). Thanks to Ph.D. Iliana Medina–Ramírez for document improvement.
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