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TIP. Revista especializada en ciencias químico-biológicas
versão impressa ISSN 1405-888X
TIP vol.12 no.2 Ciudad de México Dez. 2009
Artículos de revisión
Métodos no enzimáticos de isomerización de aldosas a cetosas
1 Depto. de Ciencias Básicas, Instituto La Salle de Investigaciones Avanzadas, ISIA, Vicerrectoría de Investigación y Transferencia, Universidad de La Salle. Carrera 5, No 59A-44, Edif. Hno. Justo Ramón, Piso 7, Bogotá, Colombia. E-mail: efonsecas@unisalle.edu.co
La isomerización enzimática y no enzimática de aldosas a cetosas es un proceso ampliamente estudiado, sin embargo, mientras que la tecnología que emplea enzimas se encuentra madura, las tecnologías no enzimáticas no se encuentran totalmente desarrolladas. El objetivo de esta revisión es presentar la selectividad y eficiencia de las alternativas reportadas en la literatura para la interconversión no enzimática de aldosas a cetosas con el fin de evaluar la factibilidad de su empleo en la industria de los alimentos. De los métodos analizados, aparentemente el más promisorio es el que emplea líquidos iónicos, ya que es rápido y ampliamente selectivo, sin embargo, desarrollar la tecnología que emplee este tipo de líquidos para la interconversión de un par aldosacetosa en particular es una tarea pendiente en la que los investigadores tendrán que trabajar en los próximos años.
Palabras Clave: Aldosa; cetosa; eficiencia; interconversión; selectividad
The enzymatic and non-enzymatic isomerization of aldoses to ketoses is a widely studied process. However, while the technology that uses enzymes is mature, non-enzymatic technologies are not fully developed. The objective of this review is to present the selectivity and efficiency of the alternatives reported in the literature for non-enzymatic interconversion of aldoses-ketoses, in order to evaluate the feasibility of its use in the food industry. Of the methods analyzed, the most promising are the ones that use ionic liquids due to the fact that they are fast and largely selective, but developing the technology that uses this type of liquids for the interconversion of a particular aldose-ketose pair is a challenge for research in the coming years.
Keywords: Aldose; ketose; efficiency; interconversion; selectivity
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Recibido: 02 de Octubre de 2009; Aprobado: 11 de Noviembre de 2009
Este es un artículo publicado en acceso abierto bajo una licencia Creative Commons
