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Rev. mex. cienc. geol vol.29 no.2 México ago. 2012
Island arc tholeiites of Early Silurian, Late Jurassic and Late Cretaceous ages in the El Fuerte region, northwestern Mexico
Toleitas de arco insular del Silúrico Temprano, Jurásico Tardío y Cretácico Tardío en la región de El Fuerte, noroeste de México
Ricardo VegaGranillo*, Jesús Roberto VidalSolano, and Saúl HerreraUrbina
Departamento de Geología, Universidad de Sonora, Rosales y Encinas s/n, 83000 Hermosillo, Sonora, México. *firstname.lastname@example.org
Manucript received: November 3, 2011.
Corrected manuscript received: April 18, 2012.
Manuscript accepted: April 24, 2012.
Three distinctive igneous suites crop out in the El Fuerte block, northwestern Mexico. The oldest of these suites is the Realito Gabbro, which intrudes the MiddleUpper Ordovician Río Fuerte Formation. This gabbro yielded an Early Silurian UPb zircon age of ca. 430 ± 15 Ma. The Topaco Formation is a greenschist facies metamorphosed volcanosedimentary sequence. Basaltic rocks of this unit yielded a Late Jurassic UPb zircon age of 155 ± 3.5 Ma (Kimmeridgian). The Guamuchil Formation mainly consists of basaltic flows overprinted by greenschist facies contact metamorphism. A sample of this unit yielded a Late Cretaceous UPb zircon age of 73 ± 1.5 Ma (Campanian). Geochemical signatures of the three suites suggest an island arc tholeiitic environment. The Upper Jurassic Cubampo Granite is a peraluminous subalkaline granite. Age coincidence and similarities in rare earth element patterns and trace elements concentrations suggest that a genetic link exists between the Cubampo Granite and the Topaco Formation. In a regional context, the Realito Gabbro is coeval with Silurian rocks of the Acatlán Complex in southern Mexico, although geochemical data indicate they originated in different tectonic settings. In a larger scale, the Realito Gabbro rocks are coeval with rocks located along the Appalachian chain and northwestern South America. Late Jurassic magmatism in the El Fuerte region may be the southern prolongation of the continental magmatic belt of Sonora and southwestern USA. Late Cretaceous magmatism of the Guamuchil Formation may correlate with the SonoraSinaloa belt of intrusive and volcanic rocks, which was emplaced after accretion of the Guerrero terrane. The island arc tectonic setting indicated by geochemistry of the Mesozoic suites in the El Fuerte region differs from the continental arc setting of northcentral Sonora and southwestern USA, which is probably due to mantle source differences.
Key words: island arc magmatism, Early Silurian, Late Jurassic, Late Cretaceous, El Fuerte, Sonobari, Sinaloa, Mexico.
En el bloque El Fuerte, situado al norte del estado de Sinaloa en el noroeste de México, afloran tres grupos ígneos distintivos. La unidad más antigua es el Gabro Realito, el cual intrusiona a la Formación Río Fuerte del Ordovícico MedioSuperior. Este gabro produjo una edad UPb en zircones de ca. 430 ± 15 Ma, correspondiente al Silúrico Temprano. La Formación Topaco es una secuencia volcanosedimentaria con metamorfismo en facies de esquisto verde. Análisis UPb en zircones separados de una roca basáltica de esta unidad produjo una edad de 155 ± 3.5 Ma (Kimmeridgiano). La Formación Guamúchil está formada principalmente por flujos basálticos con un metamorfismo de contacto en facies de esquisto verde. En una muestra de esta unidad se obtuvo un edad UPb en zircones de 73 ± 1.5 Ma (Campaniano). La firma geoquímica de los tres grupos es muy similar e indica que corresponden a toleítas de arco de islas. Las características geoquímicas del Granito Cubampo del Jurásico Superior y rocas relacionadas, indica que se trata de un granito subalcalino peraluminoso. Similitudes en las concentraciones de elementos de las tierras raras y otros elementos traza entre el Granito Cubampo y las rocas máficas de la Formación Topaco sugieren algún tipo de relación genética entre ambas unidades. En un contexto regional, el Gabro Realito es contemporáneo de las rocas silúricas del Complejo Acatlán que afloran en el sur de México, aunque diferencias geoquímicas y en las condiciones de metamorfismo indican que los contextos tectónicos para ambas regiones fueron diferentes. En una escala mayor, el Gabro Realito es contemporáneo de rocas localizadas a lo largo de la cadena apalachiana o en el noroeste de América del Sur. Considerando su edad, el magmatismo del Jurásico Tardío en la región de El Fuerte puede corresponder con la prolongación al sur de un cinturón magmático continental que se extiende a través de Sonora desde el suroeste de los EUA, o bien, puede corresponder al magmatismo del Jurásico TardíoCretácico Temprano del terreno compuesto Guerrero. El magmatismo del Cretácico Tardío de la Formación Guamúchil puede relacionarse al cinturón magmático de SonoraSinaloa, formado por rocas intrusivas y volcánicas emplazadas después de la acreción del terreno Guerrero. El contexto tectónico de arco de islas indicado por la geoquímica de las rocas mesozoicas en la región de El Fuerte difiere del contexto de arco continental de Sonora centralnorte y suroeste de los EUA, lo cual se considera producido por diferencias en la fuente mantélica.
Palabras clave: magmatismo de arco insular, Silúrico Temprano, Jurásico Tardío, Cretácico Tardío, El Fuerte, Sonobari, Sinaloa, México.
The El Fuerte block consists of metamorphic rocks that crop out in northern Sinaloa, about 300 km south of the Laurentian craton boundary (Figure 1). This block is a piece of a late Paleozoic orogen located outboard of the SonoraMarathonOuachita foldandthrust belt (Poole et al., 2005). That location suggested an exotic origin that contrasts with the Laurentian blocks of central and northern Sonora (Poole et al., 2005). The basement of the El Fuerte block is the Sonobari complex (de Cserna and Kent, 1961; Campa and Coney, 1983). This complex is comprised by the Middle to Upper Ordovician Río Fuerte Formation (Mullan, 1978; Poole et al., 2005; VegaGranillo et al., 2008) and the Late Jurassic Topaco Formation (VegaGranillo et al., 2008), which crop out east of the El Fuerte town, as well as the Late Triassic (?) Francisco Gneiss (Mullan, 1978; Anderson and Schmidt, 1983; Keppie et al., 2006) which crops out west of the El Fuerte town. Detrital zircon data from the Río Fuerte Formation indicate a periGondwanan provenance (VegaGranillo et al., 2008). The terranes map of Campa and Coney (1983) shows that the Sonobari Complex is surrounded by the Guerrero Terrane or superterrane (inset in Figure 1). This terrane is composed by Upper Jurassic to Lower Cretaceous volcanic, volcanosedimentary and minor sedimentary rocks (Campa and Coney, 1983), deposited over a Late Triassic metamorphosed basement (CentenoGarcía et al., 1993).
This study deals with three igneous units cropping out in the El Fuerte area, which lack detailed geochemical or isotopic studies. Tentative ages of Late Cretaceous, Late Jurassic, and Early Cretaceous, were previously proposed by Mullan (1978) for the Realito Gabbro, Topaco Formation and Guamuchil Formation, respectively, based on petrology, geological relationships, and correlations. In this work, we present a UPb geochronology study, aimed to obtain precise ages. Additionally, geochemical analyses of major, minor, and rare earth elements, were performed on selected rocks of each unit to identify their geochemical affinity and tectonic setting. Based on these data, a list of the igneous units that may correlate with those of the study area is included, and the probable associated tectonic scenarios are discussed.
UPb isotopic ratios of zircons were measured by laser ablation multicollector inductively coupled plasma mass spectrometry (LAMCICPMS) at the University of Arizona LaserChron Center using the procedures described by Gehrels et al. (2006).
Mineral composition was determined using a CAMECA SX100 electron microprobe at the Department of Lunar and Planetary Sciences of the University of Arizona. For the geochemical measurements in whole rock, samples were ground first in a steel jaw crusher and then finely powdered in an agate grinder. Major and compatible trace elements were quantified by inductively coupled plasma atomic emission spectrometry (ICPAES), whereas rare earth elements (REE) and additional trace elements were obtained for a subset of samples by inductively coupled plasmamass spectrometry (ICPMS) at ALS Chemex laboratory. Some major element compositions were obtained using a Bruker SRS3400 WDXRF spectrometer at the "Laboratorio de Cristalografía y Geoquímica del Departamento de Geología" of the Universidad de Sonora. Analytical errors are 13% for major elements and about 3% for trace elements.
The Río Fuerte Formation is the oldest unit in the study area (Figure 2). This unit consists of greenschist to amphibolite metasedimentary rocks (VegaGranillo et al., 2011) containing Middle to Late Ordovician conodonts (Poole et al., 2005). Detrital zircons data indicate deposition in an intraoceanic basin located between an Ordovician arc and an extinct periGondwanan arc (VegaGranillo et al., 2008). The Río Fuerte Formation underwent at least two low P/T (Buchan type) metamorphic events, which are coeval with two deformational phases (VegaGranillo et al., 2011).
The greenschist metamorphosed Cubampo Granite and related aplite sills intrude the Río Fuerte Formation yielding ages of 155 and 151 Ma, respectively (UPb, zircon; VegaGranillo et al., 2008). The Realito Gabbro, also intruding the Río Fuerte Formation (Figure 3), was tentatively considered as Late Cretaceous in age (Mullan, 1978), but a precise age is presented in this work.
The Topaco Formation is a greenschist metamorphosed volcanic and volcaniclastic unit assigned to the Late Jurassic (Mullan, 1978) on the basis of geological relationships. Metaagglomerates of this unit contain clasts of the Upper Jurassic Cubampo aplite as well as clasts of the Río Fuerte Formation (VegaGranillo et al., 2011). The Río Fuerte Formation is thrust over the Topaco Formation. Although precise ages for metamorphic events in the El Fuerte units are unknown, the first event affecting only the Río Fuerte Formation must have occurred between the Late Ordovician and Late Jurassic times; and the second, imposed on both, the Río Fuerte and Topaco formations, may be Late Jurassic in age (VegaGranillo et al., 2008).
The Guamuchil Formation is a thick unit made of lava flows with greenschist facies contact metamorphism, which structurally overlies the Río Fuerte and Topaco formations. In turn, this unit is overlain by ~100 m of slightly recrystallized micritic limestones named Los Amoles Formation (Mullan, 1978), in which no fossils have been founded. In spite of lacking fossils, limestones of this unit were tentatively correlated with fossiliferous AlbianCenomanian beds of the Alisitos Formation from Baja California (Mullan, 1978). Based on that correlation, the Guamuchil Formation was considered as the volcanic lower section of the Alisitos Formation, and consequently, of Early Cretaceous age (Mullan, 1978). However, a precise age for the Guamuchil Formation is included in this work. Granodioritic to dioritic bodies referred to as the Capomos Granite intrudes all previous units. These intrusives yielded KAr biotite ages of 57.2 ± 1.2 Ma (Damon et al., 1983).
This unit includes three small gabbro intrusions (<1 km wide) outcropping near the town of Realito (Figure 3). Mafic dikes crosscut the gabbro and are regarded as part of the same suite by their close field relationship. The gabbro plutons intrude the Río Fuerte Formation and, in turn, both units are intruded by the Upper Jurassic Cubampo Granite and the Paleocene Capomos Granite (Figure 1).
The Realito Gabbro is composed of large amphibole crystals containing anhedral relics of AlCr diopside. Amphibole and pyroxene classification diagrams are included in Figure 4. Metamorphic minerals partially replaced the gabbro original mineralogy during regional and/or contact metamorphism events; in particular, plagioclase is absent due to total replacement by secondary minerals. Secondary finegrained clinozoisiteepidote, chlorite, and actinolite, surround large amphibole crystals. Amphibole zoning is complex including Mghornblende cores with Mghastingsite and pargasite rims, which in turn, are irregularly replaced by zones of actinolite and minor tremolite. Mafic dikes cutting the gabbro display an incipient foliation and are made of fibroradial amphibole and labradorite, with secondary zoisite, chlorite, titanite, and calcite. Thin veinlets of quartz + chlorite + calcite + epidote crosscut the gabbro and dikes.
This unit includes an irregular shaped granite stock, aplitic dikes and sills, as well as isolated enclaves of mediumgrey color. These rocks intrude the Río Fuerte Formation and the Realito Gabbro (Figures 1 and 3). Aplite sills emplaced along the Middle to Upper Ordovician Río Fuerte metasedimentary rocks were originally considered as a rhyolite flow and used as stratigraphic marker (Mullan, 1978); however, a sill yielded a 155 ± 4 Ma age confirming its intrusive character (VegaGranillo et al., 2008). The main Cubampo body and related sills are characterized by nodules of quartz as large as 1.5 cm. Mineralogy consists of Kfeldspar, quartz, plagioclase, and minor muscovite, biotite, titanite and zircon. Retrogressive metamorphic minerals are epidotezoisite, chlorite, tremolite, and sericite. Foliation is incipient in the main granitic body and more developed in the finegrained aplite sills, occurring as aligned chloritesericiteepidote grains.
This unit mostly consists of metaagglomerates, some intercalated metabasites, scarce metarhyolite, slate, quartzite, and minor mafic dikes, with a structural thickness varying from 1300 to 5000 m. Clasts in metaagglomerates are petrographically similar to rocks of the Río Fuerte Formation and the Cubampo Granite. One nodular aplite clast from the metaagglomerate yielded a 151 ± 1 Ma age (UPb zircon, VegaGranillo et al., 2011) coincident with the ages of the Cubampo Granite and related sills. The Topaco Formation displays mesoscopic welldeveloped pervasive foliation, which is parallel to the S2 foliation of the Río Fuerte Formation. Structural relationships indicate the Río Fuerte Formation is thrust over the Topaco Formation (VegaGranillo et al., 2011).
Two samples of the Topaco Formation were collected for geochemical and geochronological studies. Sample ELF205 is a mafic flow made of plagioclase phenocrysts and amphibole clusters in a groundmass of finegrained plagioclase, amphibole, with accessory biotite and titanite. Sample ELF206 is a diorite dike crosscutting andesite metaagglomerates. Diorite consists of prismatic phenocrysts of amphibole surrounded by plagioclase + quartz groundmass. Plagioclase displays zoning from labradorite to andesine and some myrmekite overgrowths. Amphibole has Mghornblende cores and actinolite rims (Figure 4). Metamorphic minerals like actinolite, epidote, chlorite, white mica, and calcite, partially replaced primary minerals, occurring also as thin veinlets.
This unit consists of darkgreen to black volcanic flows, minor agglomerate and tuff. Mafic rocks display porphyritic to glomeroporphyritic texture, with plagioclase phenocrysts in clusters or isolated, in a groundmass of amphibole + plagioclase. Some metabasites contain spheroidal clusters of coarsegrained amphibole. Amphibole is mainly tschermakite, with minor Mghornblende, and outer rims of tremolite (Figure 4). Plagioclase is zoned with bytownite cores and oligoclase rims. Groundmass is made of secondary biotite + epidote + titanite + quartz. Mesoscopic lenses and layers of palegreen epidote, amphibole, quartz, chlorite and opaque minerals, are originated by hydrothermal metamorphism. Veinlets and lenses of amphibole ± quartz ± opaque minerals are common. Intermediate flows interbedded with metabasite consist of andesine phenocrysts in a groundmass of plagioclase + Kfeldspar + quartz + biotite (e.g., ELF214). Some of these rocks display a poorly developed foliation.
Mafic rocks of the Realito Gabbro, Topaco and Guamuchil formations were sampled for UPb zircon geochronology (Table 1, Figure 5), location of samples is included in Table 2. Sample ELF202 from the Realito Gabbro is a coarsegrained hornblendepyroxene gabbro. Very few zircons obtained from this sample are light pink in color, with euhedral to subhedral shape. Four zircons yielded a mean weighted age of 430 ± 15 Ma (Llandovery) with a MSWD of 0.6 (Figure 5a). Dated zircons have Th/U ratios from 0.5 to 2.3 suggesting a magmatic origin, provided that metamorphic zircons usually have Th/U ratios <0.07 (Rubatto, 2002). Five younger ages varying from Mississippian to Late Cretaceous are mostly isolated and are considered as produced by Pbloss related with later metamorphic events, although one Late Jurassic (156 Ma) and one Early Cretaceous (144 Ma) ages are also concordant.
In the Topaco Formation sample (ELF205), six light pink, euhedral to subhedral zircons making the only cluster of the sample yielded a mean weighted age of 155 ± 3.5 Ma age (Kimmeridgian) with a MSWD of 1.3 (Figure 5b). Besides these six zircons, only one inherited Precambrian zircon was dated. Because no younger ages were obtained and Th/U ratios vary from 0.26 to 0.61, the Late Jurassic age is considered representative of the magmatic age of the sample.
The Guamuchil Formation dated sample (ELF219) is a finegrained mafic rock made up of amphibole and plagioclase, with pseudomorph lenses of zeolite + chlorite ± amphibole. Fourteen dated zircons yielded an age of 73 ± 1.5 Ma (Campanian) with a MSWD of 1.5 (Figure 5c), interpreted as indicating its magmatic crystallization. Older ages are considered as coming from inherited zircons.
Major and trace element compositions of all dated igneous units from the El Fuerte area were obtained (Table 3) and its location included in Table 2. Major element compositions were normalized to 100% on a volatilefree basis before being plotted. Some altered rocks were studied to see how metamorphism might have modified their geochemical composition; anyway, most rocks display coherent distribution of major elements and therefore, metamorphism is assumed to be mostly isochemical.
The Realito Gabbro has a subalkaline character with low TiO2 (<0.7 wt.%), low SiO2 and low alkalis contents (Figure 6a). The low ratios of the high field strength (HFS) elements Nb/Y and Zr/Ti (Figure 6b), which are generally immobile (Rollinson, 1993) confirm this feature. High FeOt concentration shows a typical tholeiitic signature (Figure 7a and 7b). The gabbro is characterized by its high content of MgO (~18 wt.%), Ni, Cr, and Co.
Finegrained mafic dikes cutting the Realito Gabbro have tholeiitic composition, higher Al2O3, but lower MgO, Ni, Cr and Co, than the host rock. ELF 225 sample is richer in SiO2 and Zr than the coarsegrained gabbro, but remains in the gabbro field (Figure 6a and 6b). Rare earth element (REE) spectra normalized to chondritic values of Sun and McDonough (1989) and incompatible multielement patterns normalized to MORB (Pearce, 1983) relate gabbro and its crosscutting dikes (Figure 8a and 8d). Both types of rock are slightly enriched in light rare earth elements (LREE) [(La/Yb)N = 3.40 4.25], and depleted in heavy rare earths elements (HREE). REE abundances are mostly lesser than 10X the chondritic relation. This feature distinguishes microgabbro dikes from rocks of the Topaco and Guamuchil formations (Figure 8a, 8c). MORBnormalized multielement spectra of the Realito Gabbro and microgabbro display enrichment of lowfield strength (LFS) elements and depletion of highfield strength (HFS) elements (Figure 8d). Their patterns are characterized by 1) forming a hump in CeP, and a more pronounced one in Rb, Ba and Th; and 2) slight negative anomalies in Nb. Gabbro and microgabbro normative composition includes plagioclase (Pl), olivine (Ol), diopside (Di), and hypersthene (Hy), which is distinctive of olivine tholeiites (Yoder and Tilley, 1962).
High content in MgO (~18%), Ni, Cr, and Co, in the Realito Gabbro suggests either a komatiitic affinity or derivation of a cumulate process. According to Seiferd et al. (1996) cumulate gabbros have lost most of the incompatible elements, which is specially obvious in the REE diagram, where they display REE abundance between 1X to 5X chondrite, while isotropic gabbros have abundances near or above 10X chondrite (Seiferd et al., 1996). Both, the Realito gabbro and dikes have REE abundance lesser than 10X chondrite coinciding with those described for cumulate gabbros (Seiferd et al., 1996). Although a cumulate origin can be proposed for the coarsegrained gabbro, this cannot be done for the dikes. An alternative explanation for the low REE abundances in both gabbro and microgabbro is a high degree of partial melting in the source (Best, 2003).
Cubampo Granite and related dikes correspond to peraluminous subalkaline granites with normative corundum (Figure 6a). Granites have high SiO2 (75 78 wt.%) and Fe (2.2 3.4 wt.%) content. An enclave within the granite has quartzdiorite composition. All samples display a regular increase in LREE, a strong negative anomaly in Eu, and flat patterns for the HREE (Figure 8b) relative to chondrite. The aplite sample has a more depleted LREE and enriched HREE spectra. In the multielement diagram, felsic rocks display spiky patterns due to: (1) a pronounced hump in Th and most largeion lithophile (LIL) elements; (2) negative anomalies in Sr, P, and Ti; (3) muchless significant ones in NbTa (Figure 8e).
The samples of the Topaco Formation, as those of the Realito Gabbro, have subalkaline mafic composition, tholeiitic affinity, similar concentration of REE [(La/ Yb)N = 3.33.4], as well as low Ti and high Fe contents. Nevertheless, the Topaco Formation rocks have higher silica (5253 wt.%) and alkalis (2.773.61 wt.%) content (Figure 6a). In addition, REE and multielements patterns are more enriched than those of the Realito Gabbro, although they are mostly parallel (Figure 8a, 8b, 8d and 8e). In addition, normative minerals in the Topaco Formation are quartz (Qtz), plagioclase (Pl), diopside (Di), and hypersthene (Hy), which is representative of quartz tholeiites (Yoder and Tilley, 1962). Similarities in REE and trace elements concentrations between Cubampo Granite rocks and mafic rocks of the Topaco Formation suggest some kind of genetic link between them, maybe peraluminous granites were formed after crustal heating by mafic magmas.
Upper Cretaceous lava flows of the Guamuchil Formation include basaltic andesites, minor basalt, and andesite, all of which have a subalkaline composition (Figure 6a and 6b). These rocks show considerable variation in chemical composition, exemplified by the SiO2 content from 45 to 66 wt.% (on a volatile free basis). Silica content under 45 wt.% may imply a process of alkalinebasic metasomatism, which cause depletion of acid (SiO2, F, Cl, SO3, CO2, etc.) and input of alkaline/basic (K2O, Na2O, CaO, MgO, etc.) components (Zharikov et al., 2007). Samples with low silica of the Guamuchil Formation have higher Ti values than those of the Realito and Topaco formations (0.8 1.4 wt.%). Basalt and basaltic andesite are alumina rich (14 19 wt. %), with tholeiitic character, which is evidenced by a Fenner trend (Fenner, 1937) in the Al2O3FeOMgO (AFM) diagram (Figure 7b). REE and multielements patterns of the Guamuchil Formation (Figure 8c and 8f) are indistinguishable of those of the Topaco Formation (Figure 8b and 8e), and both units have the same normative minerals including Qtz, Cpx, Opx and Pl, indicating they are quartz tholeiites (Yoder and Tilley, 1962).
Metamorphism has affected the primary concentrations of SiO2 and some trace elements in some rocks of the Realito Gabbro, as indicated by higher loss on ignition (LOI) (e.g. ELF 226B and ELF 226C) and changes in REE patterns (Figure 8). Altered dikes have higher depletion in most REE excepting La, Eu, and Tm.
In few samples of the Guamuchil Formation, hydrothermal metamorphism replaced original minerals by epidote, actinolitetremolite, and chlorite. This process is responsible for variation in concentrations of major elements. For example, metasomatic SiO2 loss in sample ELF 219 originated its plotting in the ultramafic field (Figure 6a), and a sodic alkaline character marked by the presence of leucite and nepheline in the CIPW norm. In spite of variation in major elements of samples ELF 219 and ELF 217 (Figure 6a), ratios of immobile HFS elements (Nb/Y vs. Zr/ Ti, Figure 6b) and the REE patterns (Figure 8c) are identical to those of other samples in this formation (Figure 8a and 8b); while the multielement patterns display lower content of K, Rb, and Ba, in the altered samples (Figure 8f). Only the ELF 214 sample displays a differentiated composition with more enriched LREE concentration and subtly negative anomaly in Eu (white triangle in Figure 8c).
In order to elucidate the tectonic setting that the El Fuerte samples are more akin, a comparison between analyzed multielement spectra of the El Fuerte units and those of basalts in present tectonic environments was carry out using the diagram of Pearce (1983) modified by Wilson (1989) (Figure 9a). In this diagram, signatures of the El Fuerte basalts are analogous to those of oceanic island arc environments, with the Guamuchil Formation spectra more similar to oceanic island arc calcalkaline basalts and those of the Realito Gabbro with a trend to oceanic islandarc tholeiitic basalts. In addition, samples were plotted in the TiV diagram of Shervais (1982), which is adequate because these elements are immobile under conditions of hydrothermal alteration and at intermediatetohigh grades of metamorphism (Rollinson, 1993). In the TiV diagram, rocks of the Realito Gabbro and Topaco Formation clearly fall in the field of arc tholeiite (Figure 9b). The Guamuchil Formation samples fall in either the arc tholeiite, calcalkaline, or midocean ridge basalts (MORB) and backarc basin (BAB) fields. In order to discriminate between the overlapping fields of the TiV diagram for the Guamuchil Formation, we use the TiZrSr/2 diagram of Pearce and Cann (1973). In this diagram, basalts of the Guamuchil Formation fall in the islandarc tholeiite field (Figure 9c) far from the MORB field. Although Rollinson (1993) indicates that the TiZrSr/2 diagram can only be used for fresh samples because of the relative mobility of Sr, the coherent behavior of this element in all samples suggests that no major alterationrelated dispersion has occurred.
Lower Silurian Realito Gabbro
Silurian magmatic rocks are scarce in Mexico. In our knowledge, only the Acatlán Complex basement of the Mixteco terrane in southern Mexico includes rocks of this age (location in Figure 10). There, batholitic granite with 440442 Ma UPb zircon ages (OrtegaGutiérrez et al., 1999; TalaveraMendoza et al., 2005; VegaGranillo et al., 2007) intrudes into sedimentary rocks and, in turn, basaltic dikes crosscut both types of rock. Subsequently, all of these rocks, grouped as the Esperanza suite, underwent eclogitic metamorphism (VegaGranillo et al. , 2007). However, some unmetamorphosed granites of the Acatlán Complex, also regarded as the Esperanza Granitoids, yield Late Ordovician ages (e.g., Keppie et al., 2008). The age of the eclogitic metamorphism is either Lower Silurian (430 ± 10 Ma, 39Ar/40Ar isochron) obtained dating amphibole in eclogite (VegaGranillo et al., 2007), or Late DevonianMississippian (e.g., ElíasHerrera et al., 2004; Murphy et al. , 2006). Esperanza metagranitoids are peraluminous with calkalcaline continental arc signature (RamírezEspinosa, 2001), while the mafic rocks have characteristics of withinplate continental tholeiites (Murphy et al., 2006). In a wider context, Silurian magmatism occurs in the Maya mountains of Belize (Martens et al., 2010), the Appalachian chain (e.g., Whalen et al., 2006), and northwestern South America (Chew et al., 2007). For example, Silurian plutonic suites in the Newfoundland Appalachians include abundant gabbro, monzogabbro and granite to granodiorite and lesser quartzdiorite and tonalite. Mafic rocks include both arclike (Nb/Th<3) calcalkaline, and nonarclike (Nb/Th>3) transitional calcalkaline basalt to continental tholeiitic affinity compositions (Lissenberg et al., 2006; Whalen et al., 2006). Gabbro complexes have ages from 435 ± 1 to 430 ± 2 Ma (Lissenberg et al., 2006; Whalen et al., 2006). In the Eastern Cordilleras of Perú and Ecuador, subductionrelated magmatic rocks yielded ages of 474 to 442 Ma (Chew et al., 2007), but its geochemical character is unknown.
In order to review the probable relation between the Acatlán complex, the Río Fuerte Formation and the Granjeno Schist from southern, northwestern and northeastern Mexico respectively, detrital zircon plots from metamorphic units of each region (data from TalaveraMendoza et al., 2005; VegaGranillo et al., 2008; BarbozaGudiño et al., 2011) were tested through the similarityoverlap method described by Gehrels (2000). Degree of overlap is the degree to which the two age probabilities overlap; there, 1.0 is a perfect overlap, 0.0 indicates no overlap occurs. Degree of similarity is a measure of whether proportions of overlapping ages are similar. Higher values (up to 1.0) reflect similar proportions of overlapping ages. Lower values (down to 0.0) reflect different proportions of ages that may or may not overlap. Results of that comparison, displayed in Table 4, indicate the El Fuerte detrital zircon plots have larger overlap and similarity with those of the Cosoltepec and Ixcamilpa formations of the Acatlán Complex, being both noteworthy high (overlap from 0.74 to 0.81 and similarity from 0.67 to 0.78). However, the Middle to Late Ordovician age of the Río Fuerte Formation precludes correlation with the Cosoltepec Formation because this later unit is considered Early Devonian or younger in age (e.g., TalaveraMendoza et al., 2005). Besides, the Río Fuerte detrital zircon plots are comparable with those obtained in the Granjeno Schist from Tamaulipas and Nuevo León, Mexico (BarbozaGudiño et al., 2011) with overlap from 0.86 to 0.77 and similarity between 0.74 and 0.55 (Table 4). In the Table 4, it is also noteworthy the high similarity between some units of the Granjeno Schist with some units in the Acatlán Complex.
Upper Jurassic Cubampo Granite and Topaco Formation
The Late Jurassic ages of the Cubampo Granite and related dikes (VegaGranillo et al., 2008; 2011) are coeval within analytical errors with the age obtained from the metabasite of the Topaco Formation. Similarities in REE and trace elements concentrations between these two types of rocks, also suggest they are genetically related.
At regional scale, Jurassic magmatic rocks occur in two areas: 1) southwestern Arizona, southeastern California and northwestern Sonora (Tosdal et al., 1989); and 2) Central Mexico (Figure 10). Both areas have been considered as parts of a continuous Late TriassicMiddle Jurassic magmatic arc (Bartolini et al., 2003), or as parts of a truncated arc displaced about 800 to 1000 km to southeast by the MojaveSonora megashear (e.g., Anderson et al., 2005; Haxel et al., 2005). In the northwestern area (1), calkalcaline magmatic rocks yielding ages between 175 and 165 Ma are interpreted as continental arc magmatism (Anderson et al., 2005; Haxel et al., 2005). In the central Mexico area (2), the Nazas Formation is a thick sequence of andesite and dacite with minor rhyolite and latite, capped by red beds (Blickwede, 2001). Welded eutaxitic tuffs in the upper part of the Nazas Formation have UPb ages of 172 and 169 Ma (Lawton, 2010). Consequently, the suites from the northwestern and central areas are older than the Cubampo and Topaco formations and cannot be correlated with them.
A regional suite of Upper Jurassic sedimentary, volcanic, and plutonic units, overlies or intrudes Middle Jurassic sequences in southwestern USA (e.g., Saleeby and BusbySpera, 1992; Anderson et al., 2005). These units (e.g., Artesa, Ko Vaya, McCoy Mountains, Glance formations) yield 165 to 145 Ma ages (e.g., Barth et al., 2004; Anderson et al., 2005; Haxel et al., 2005). The Glance Conglomerate of southwestern Arizona contains abundant rhyolitic, dacitic, and andesitic volcanic and volcaniclastic deposits interstratified with boulder brecciaconglomerates (e.g., Busby et al., 2005). Geochemical data suggest these rocks record a variation from continental arc to rift volcanism (Krebs and Ruiz, 1987; Anderson et al., 2005), or continental arc setting only (Busby et al., 2005). Two granodiorites and one metarhyolite from the Caborca terrane yielded 153 Ma, 164 Ma and 141 Ma ages, respectively (Anderson et al., 2005). In addition, ortogneisses in the eastern Peninsular Ranges in Baja California yielded a 162 Ma age (e.g. Alsleben et al. , 2008). Whereas, in Central Mexico an intrusive related to the Coapas schist yielded a 158 ± 4 Ma age (UPb zircon age, Jones et al., 1995). All previous rocks are nearly coeval to the Cubampo and Topaco dated samples.
In addition to the Late Jurassic magmatism mentioned above and considered as formed in continental arc setting, Late JurassicEarly Cretaceous magmatism occurs in the Guerrero superterrane (Figure 11c), which includes the Alisitos terrane of Baja California. Some authors consider this superterrane as relatively or partially exotic to PrecambrianPaleozoic terranes composed of Laurentian or Gondwanan blocks forming mainland Mexico (e.g., Campa and Coney, 1983; Dickinson and Lawton, 2001). However, there is no consensus about the exotic origin of the Guerrero superterrane. The Arteaga Complex, considered the basement of the Guerrero superterrane (CentenoGarcía et al., 2003), consists of metamorphosed sedimentary, volcanic and intrusive rocks assigned to the Late TriassicLower Jurassic (CentenoGarcía et al., 1993). The Tumbiscatío Granite intrudes the Arteaga Complex and yielded a UPb age of 163 Ma (CentenoGarcía et al., 2003) and a KAr age of 158 ± 5 Ma (GrajalesNishimura and LópezInfanzón, 1984). The arc assemblage of the Guerrero terrane includes basalts yielding KAr and 39Ar/40Ar ages of 105 to 93 Ma (DelgadoArgote et al., 1990; OrtizHernández and Lapierre, 1991; ElíasHerrera et al., 2000), which are covered by Lower Cretaceous sedimentary rocks (GuerreroSuástegui et al., 1993; Salinas, 1994). In Guanajuato, a magmatic sequence formed by a cogenetic islandarc tholeiitic suite, ultramaficmafic cumulate rocks, diabasic feeder dikes, and basaltic pillow lavas (Lapierre et al., 1992) yielded KAr ages ranging from 157 to 108 Ma (OrtizHernández et al., 1990; Lapierre et al., 1992). This sequence is thrust to the NNE over a contemporaneous, highly deformed, detrital and volcanic sequence named the Arperos Formation (Monod et al., 1990), which is an island arc tholeiitic suite, ranging from ultramaficmafic cumulate rocks, diabasic feeder dikes, and basaltic pillow lavas (Lapierre et al., 1992). The lowermost limestone levels of the Arperos Formation contain nannofosils of TithonianHauterivian age (CoronaChávez, 1988). Limestones with AptianAlbian fossils (Chiodi et al., 1988; QuinteroLegorreta, 1992) cover the Arperos formation.
In the Vizcaino Peninsula and Cedros Island of western Baja California, magmatism spans from the Late Triassic (221 Ma) to the Early Cretaceous (ca. 135 Ma; Kimbrough and Moore, 2003). In that region, the Upper JurassicLower Cretaceous Coloradito and Eugenia Formations contain mudflows and olistostrome blocks interbedded with arc volcanogenic sediment and riftrelated pillow lavas. Middle Jurassic to Lower Cretaceous plutonic arc rocks (ca. 165135 Ma) intrude low greenschist facies ophiolite and volcanic arc basement (Kimbrough and Moore, 2003). These intrusions are Itype Cordilleran batholithic rocks, ranging from gabbro to granodiorite, with dominant tonalite, and relatively primitive arc geochemical affinities (initial 87Sr/86Sr range from ~0.704 to 0.706), but they are distinctively calcic in nature (Kimbrough and Moore, 2003). A tonalite dated at about 155152 Ma, a gneissic tonalite of ca. 149 Ma, and a leucotonalite containing fractions with ages of 150 to 160 Ma (Kimbrough and Moore, 2003) are coeval to the Cubampo Granite.
Upper Cretaceous Guamuchil Formation
The Upper Cretaceous Guamuchil Formation is coeval with volcanic suites dispersed along the North and South America western border. Late Cretaceousearly Tertiary arc magmatism in eastcentral Sonora includes the Sonoran batholith and its volcanic equivalent the Tarahumara Formation (McDowell et al., 2001). The Tarahumara Formation includes about 2500 m of andesitic to dacitic lava, agglomerate, and volcanic breccia, with subordinate felsic pyroclastic components (McDowell et al., 2001), which yielded ages from 90 to 70 Ma (UPb zircon; KAr biotite and hornblende, e.g., McDowell et al., 2001; RoldánQuintana, 2002). Rocks ranging in age from 70 to 100 Ma (39Ar/40Ar) are common in the Peninsular Ranges province of Baja California (Tulloch and Kimbrough, 2003). In the Sinaloa batholith, which is the southward extension of the Sonora batolith, Henry et al. (2003) reported syntectonic intrusions with hornblende KAr ages between 98 and 90 Ma; and posttectonic intrusions emplaced nearly continuous between 90 and 45 Ma.
The Guamuchil Formation cannot be correlated with rocks of the composite Guerrero terrane, because the upper sedimentary part of that terrane has AptianAlbian fossils (e.g., Allison, 1955; TalaveraMendoza and GuerreroSuástegui, 2000) and the lower volcanic part has Lower Cretaceous ages (DelgadoArgote et al. , 1990; OrtizHernández and Lapierre, 1991; ElíasHerrera et al., 2000). Furthermore, the Alisitos arc accretion to the continental border occurred before 108 Ma (Wetmore et al., 2002; Alsleben et al., 2008). The Guamuchil Formation may be correlated with the La UniónZihuatanejo assemblage occurring in the Zihuatanejo subterrane, which consists of sedimentary rocks interbedded with andesitic lava flows, volcanic breccia, and tuffs. Martini et al. (2010) interpreted Late Cretaceous ~88 Ma detrital zircon ages in sedimentary rocks as probably derived from the interbedded tuff units.
Discussion on the tectonic context
In the tectonic model proposed by VegaGranillo et al. (2008), the Río Fuerte Formation deposition occurred in a basin between an active Ordovician arc and an extinct Neoproterozoic periGondwanan arc. Although the Late Ordovician arc was hypothesized on the basis of detrital zircon ages in metasediments of the Río Fuerte Formation, the Realito Gabbro may be the Early Silurian extension of this arc. Geochemical data indicate that the Realito Gabbro emplacement occurred in an island arc tectonic setting. The model of VegaGranillo et al. (2008) proposed southdirected subduction, which eventually may have caused the accretion of the Río Fuerte Formation and the Realito Gabbro to southern Laurentia, probably by CarboniferousPermian times. The accretion time is constrained by the timing of emplacement of Paleozoic slope and abyssal sequences over coeval platform sequences in Central Sonora (Poole and Madrid, 1988; Poole et al., 2005).
Detrital zircon ages and Silurian magmatism relate the Sonobari Complex of northern Sinaloa with the Acatlán Complex of southern Mexico, suggesting their proximity in Paleozoic times (Figure 11a). However, the geochemical signature, calkalkaline for the Esperanza Granitoids in the Acatlán Complex and tholeiitic for the Realito Gabbro; and metamorphic conditions, high P/T in the Ixcamilpa and Esperanza suites against low P/T for the Río Fuerte Formation, suggest those regions underwent distinctive tectonic evolutions. Whereas the high P/T metamorphism in the Ixcamilpa suite occurred along a subduction zone (VegaGranillo et al., 2007), the low P/T metamorphism in the Río Fuerte Formation is more typical of magmatic arc setting (VegaGranillo et al., 2011).
Considering the present position of the El Fuerte region, the Upper Jurassic felsicmafic magmatism of that area may have occurred in two scenarios: 1) as a southern prolongation of the Upper Jurassic continental magmatism of northwestern Sonora, eastern Peninsular Ranges and southwestern USA; or 2) as part of the Upper JurassicLower Cretaceous arc assemblages of the Guerrero superterrane (Figure 11b and Figure 12). Considering that the Cubampo Granite and related dikes intrude the Río Fuerte Formation, and clasts of these two units made part of the agglomerates in the Topaco Formation, the Upper Jurassic magmatism must have been emplaced over and/or through the Río Fuerte Formation and the Realito Gabbro. Then, if the accretion of basement sequences to the Laurentian craton occurred since late Paleozoic time, the Upper Jurassic magmatism in the El Fuerte area must be autochthonous. Besides, the Arteaga Complex, basement of the Guerrero terrane, is regarded Late TriassicLower Jurassic in age (CentenoGarcía et al., 1993) and consequently, cannot be correlated with the MiddleUpper Ordovician Río Fuerte Formation. The island arc geochemical character of the Topaco Formation differs from the coeval continental arc magmatism in northern Sonora and southwestern Arizona. Anyway, this variation may be due to differences in the mantle from which these two suites derive, which is supported by Nd and Sr isotopes and REE variations in granites from northern Sonora through northern Sinaloa (ValenciaMoreno et al., 2011).
By Late Cretaceous, the Guerrero superterrane was already accreted to mainland Mexico (e.g., Tardy et al., 1994; Alsleben et al., 2008) (Figure 11c). In this scenario, the Guamuchil Formation may be part of the Late Cretaceous magmatic arc developed along the western border of Mexico, from Sonora to Guerrero (Figure 11c). Again, particular oceanic islandarc signature of the Upper Cretaceous magmatism may derive from the particular mantle source underlying the El Fuerte region.
In the El Fuerte region northwestern Mexico, four units with igneous rocks crop out:
The Realito Gabbro yielded a 430 ± 15 Ma UPb zircon age. This unit intrudes the MiddleUpper Ordovician Río Fuerte Formation, and corresponds to hornblendepyroxene gabbro with retrogressive metamorphism. Geochemistry studies indicate rocks of this unit are subalkaline island arc tholeiite with komatiitic affinity, which may be caused by cumulate processes.
A Late Jurassic suite made up by the Cubampo Granite and the Topaco Formation. The Cubampo Granite and related aplite dikes with ages between 155 and 151 Ma are peraluminous subalkaline granites. The granite contains quartzdiorite enclaves. The 155 ± 3.5 Ma age yielded by basalts of the Topaco Formation indicates that is coeval with the Cubampo Granite. The Topaco Formation samples correspond to island arc basalts with subalkaline composition and tholeiitic affinity. Similarities in REE and trace elements concentrations between the felsic rocks of the Cubampo Granite and mafic rocks of the Topaco Formation suggest some kind of genetic link between these units, maybe peraluminous granites were formed after crustal heating by mafic magmas.
The Guamuchil Formation mainly consists of basalt and basaltic andesite with subalkaline composition, high alumina but tholeiitic character. A dated sample yielded a 73 ± 1.5 Ma (Campanian) age.
The Early Silurian age of the Realito Gabbro and previously obtained detrital zircon plots of the Río Fuerte Formation (VegaGranillo et al., 2008), suggests a relationship between the El Fuerte units and the Ixcamilpa and Esperanza suites of the Acatlán Complex of southern Mexico, although subsequently, each region underwent distinctive tectonic evolutions. Petrology and field relationships indicate that the Late Jurassic rocks of the Topaco and Cubampo units were emplaced on or through the Río Fuerte Formation, which was accreted to Laurentia since late Paleozoic time. Consequently, this magmatism is considered authoctonous. The Upper Cretaceous Guamuchil Formation must be part of a large belt of coeval intrusions and volcanic rocks extending from Sonora to Guerrero in Mexico. The islandarc tholeiitic signature of these lavas differs from the continental calcalkaline character of contemporaneous rocks, and may arise from a distinctive mantle source. At last, regarding the ages obtained from volcanic rocks of the El Fuerte region, the Lower Cretaceous lavas characteristic of the Guerrero terrane were not found in this study.
The research for this paper was financed by a CONACYT (79759) grant to Ricardo VegaGranillo. We appreciate helpful assistance of Ken Domanik for microprobe analysis, and Mark Pecha for geochronologic determinations, as well as thoroughly review by Brendan Murphy, Ryan Mathur, and two anonymous reviewers.
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