SciELO - Scientific Electronic Library Online

 
vol.56 número2Study of the Influence of Microwave and Conventional Heating on the Lipase-Catalyzed Esterification of Lauric Acid with Different AlcoholsStructural and Compositional Optimization of the LiNi0.8Co0.2O2 Electrode by New Synthesis Conditions índice de autoresíndice de materiabúsqueda de artículos
Home Pagelista alfabética de revistas  

Servicios Personalizados

Revista

Articulo

Indicadores

Links relacionados

  • No hay artículos similaresSimilares en SciELO

Compartir


Journal of the Mexican Chemical Society

versión impresa ISSN 1870-249X

Resumen

TIBHE, Gaurao D.; REYES-GONZALEZ, Miguel Ángel; CATIVIELA, Carlos  y  ORDONEZ, Mario. Microwave-assisted High Diastereoselective Synthesis of α -Aminophosphonates under Solvent and Catalyst Free-conditions. J. Mex. Chem. Soc [online]. 2012, vol.56, n.2, pp.183-187. ISSN 1870-249X.

A simple, efficient and general method has been developed for the high diastereoselective synthesis of α-aminophospho-nates through "one-pot" three-component reaction of alkyl and aryl aldehydes with (S)-α-methylbenzylamine or (S)-3,3-dimethyl-2-butylamine and dimethyl phosphite (Kabachnik-Fields reaction), which proceeds in short time using microwave irradiation under solvent and catalyst free-conditions. This method could be useful in the large-scale synthesis of α-aminophosphonates in short reaction time.

Palabras clave : Three-component Reaction; Diastereoselective Synthesis; α-aminophosphonates; Aicrowave; Green-Chemistry.

        · resumen en Español     · texto en Inglés     · Inglés ( pdf )

 

Creative Commons License Todo el contenido de esta revista, excepto dónde está identificado, está bajo una Licencia Creative Commons