Journal of the Mexican Chemical Society
versión impresa ISSN 1870-249X
GHAMMAMY, Shahriar; KHORSANDTABAR, Samira; MOGHIMI, Ali y SAHEBALZAMANI, Hajar. Oxidation of Some Organic Diols with Trialkylammonium Fluorochromates(VI), R3NH[CrO3F], (R= CH3, C2H5, C3H7 and C4H9) at Room Temperature and Under Microwave Condition. J. Mex. Chem. Soc [online]. 2009, vol.53, n.2, pp. 41-43. ISSN 1870-249X.
A mild and efficient method for the mono-oxidation of diols to the corresponding hydroxyaldehydes with trialkylammonium fluorochromates(VI), R3NH[CrO3F] (R= CH3, C2H5 C3H7 and C4H9), in solution at room temperature, and in solution under microwave radiation, is reported. The easy procedure, simple work-up, short reaction times, and excellent yields are advantages of these reagents.
Palabras llave : Trialkylammonium fluorochromates(VI); oxidants; oxidation; diols; microwave; room temperature.