Resumen

PRINCE, R. Malkiya Rasalin et al. TG/DTA studies on the oxidation and thermal behaviour of Ti-6Al-4V-B₄C coatings obtained by magnetron sputtering. J. appl. res. technol [online]. 2020, vol.18, n.3, pp.178-186.  Epub 30-Jul-2021. ISSN 2448-6736.  https://doi.org/10.22201/icat.24486736e.2020.18.3.1088.

Thermogravimetric analysis (TG) is a rapid method for the determination of protecting the ability of thin film coatings in addition to oxidation kinetics. Boron carbide (B4C) reinforced Ti-6Al-4V thin films were deposited through the magnetron sputtering coating technique. The effect of 0, 2, 4, 6 and 8 Wt. % of B4C adding on microstructure, thermal behaviour and hardness of Ti-6Al-4V-B4C coatings were investigated. Thermal analysis of Ti-6Al-4V-B4C coatings with varying percentage of B4C resulted in the establishment of an exothermic peak, for the reason that reduction in the oxidation of coating. The thermal behaviour of coating was improved by B4C addition; those coatings are recommended for practical application. It was proven that the addition of B4C not only alters the thermal stability but also transforms the mechanism of oxidation. It was absolutely unconcealed that the Ti-6Al-4V-B4C film oxidization may be a multi-staged procedure subject on the heating rate. An occurrence of formal treatment for obtaining Kissinger’s assessment mechanics for various oxidization levels is additionally valid. The addition of B4C was supported to enhance the nanohardness of the coating. The morphology, composition and structure of the thin film coatings were examined by way of SEM, AFM and XRD.

Palabras llave : Thermogravimetric analysis; differential thermal analysis; oxidation kinetics; activation energy; nanohardness.

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