Resumo

NASSAR, Amal A.; HERNANDEZ-ORTEGA, Simón; VALDES-MARTINEZ, Jesús  e  WEST, Douglas X.. Crystal and Molecular Structure of 2-Aminoacetophenone-N(3)-dimethylthiosemicarbazone. Rev. Soc. Quím. Méx [online]. 2002, vol.46, n.3, pp.251-253. ISSN 0583-7693.

Condensation of N(3)-dimethylthiosemicarbazide with 2-aminoacetophenone in anhydrous ethanol produces 2-aminoacetophenone-N(3)-dimethylthiosemicarbazone, 1, which is planar with the S1 and N1 atoms in a syn conformation. The amino group forms a bifurcated intramolecular hydrogen bond with the sulfur and the imine nitrogen, and an intermolecular hydrogen bond with the thione sulfur of a second molecule.

Palavras-chave : Thiosemicarbazones; Crystal structure; X-Ray.

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